Carbon, nitrogen, and phosphorus atoms get reused again and again. One carbon atom can sit in the air as CO2, get built into glucose by a maple leaf, pass into a caterpillar, and return to the air when the caterpillar respires.
The carbon cycle runs on two opposite reactions. Photosynthesis (6CO2+6H2O→C6H12O6+6O2) pulls carbon out of the air, and cellular respiration reverses it. Longer-term stores include ocean water, shells and limestone (CaCO3), soil, and fossil fuels.
Nitrogen makes up 78% of the air, but most organisms can't use N2 because its triple bond is so strong. Microbes handle many of the conversions. Biological fixation turns N2 into ammonia, nitrification turns ammonium into nitrite and then nitrate, plants absorb nitrate or ammonium and build nitrogen into organic molecules (assimilation), decomposers release ammonium from dead matter and waste (ammonification), and denitrification returns nitrogen to the air as N2.
Phosphorus has no major atmospheric reservoir, although trace amounts occur in gases. Weathering rocks release phosphate, which moves through soil, water, and food webs and settles into sediment that can become rock over millions of years.
Worked example. A forest plot absorbs 1,200 g of carbon per square meter per year through photosynthesis. Plants respire 550 g C/m² and decomposers respire 500 g C/m² that year. If there are no other carbon transfers, net storage is 1200−550−500=150 g C/m² per year, so the forest is a carbon sink. If a fire also released 300 g C/m² that year, the net would be 150−300=−150 g C/m² per year, and the forest would become a carbon source.
- Nitrogen fixation: The conversion of atmospheric N2N_2N2 into usable nitrogen compounds. Bacteria such as Rhizobium and the industrial Haber-Bosch process produce ammonia, while lightning forms nitrogen oxides that can lead to nitrate.
- Nitrification: The microbial conversion of ammonium into nitrite and then nitrate. Plants can absorb both nitrate and ammonium.
- Denitrification: The bacterial conversion of nitrate back into N2N_2N2 gas, which returns nitrogen to the atmosphere.
- Weathering: The slow breakdown of rock by water and chemicals, which is the main natural source of phosphate for ecosystems.
Check yourself: A farmer plants clover in a field before growing corn. Why does this add nitrogen to the soil? (Answer: Clover is a legume whose root nodules hold Rhizobium bacteria that fix N2 from the air into ammonia. When clover material decomposes, some of its nitrogen can become available to the corn.)
| Feature | Carbon | Nitrogen | Phosphorus |
|---|
| Main atmospheric form | $CO_2$ | $N_2$ (78% of air) | No major atmospheric form |
| Largest reservoir | Rocks and ocean | Atmosphere | Rocks and sediment |
| How it enters living things | Photosynthesis | Plant uptake of nitrate or ammonium, or fixation by some microbes | Plants absorb phosphate from soil and water |
| Used to build | All organic molecules | Proteins and nucleic acids | DNA, RNA, ATP, phospholipids |
| Relative speed | Fast in living things, slow in rock | Moderate, depends on bacteria | Slowest |