Practice 5 is the heaviest-weighted practice on the MCQ section, covering 35 to 42 percent of those questions. You extract numbers from text, graphs, and tables; select the correct equation or definition; carry out a logical calculation; and report the answer with correct units and significant figures. This practice spans every quantitative topic: stoichiometry, gas laws, thermodynamics, electrochemistry, kinetics, equilibrium, and acid-base chemistry.
- Significant figures: The number of meaningful digits in a measured or calculated value, determined by the least precise measurement used in the calculation.
- Unit tracking: Carrying units through every step of a calculation and canceling them to confirm the answer has the correct unit for the quantity being found.
- Equation selection: Identifying which relationship or formula applies to the given situation before substituting values, such as choosing the Henderson-Hasselbalch equation for a buffer rather than the full ICE table approach.
Given a titration curve, read the equivalence point volume, calculate the moles of analyte, and determine the concentration of the original acid solution. Check that your units cancel correctly at each step.
| Topic area | Key equations or relationships |
|---|
| Stoichiometry | Mole ratios from balanced equations, molar mass, molarity = moles/volume |
| Thermodynamics | delta G = delta H - T delta S, delta G = -nFE, Hess's law |
| Kinetics | Rate = k[A]^m[B]^n, integrated rate laws, Arrhenius equation |
| Equilibrium | Keq expression, Q vs. K comparison, ICE table |
| Electrochemistry | E_cell = E_cathode - E_anode, delta G = -nFE, Nernst equation |