Photochemical smog formation refers to the process by which sunlight reacts with pollutants such as nitrogen oxides and volatile organic compounds (VOCs) in the atmosphere to create harmful secondary pollutants like ozone and particulate matter. This type of smog is particularly common in urban areas with heavy traffic and industrial activities, where emissions from vehicles and factories release these precursor chemicals into the air. The result is a thick, hazy air quality that can cause serious health issues and environmental damage.