🥼organic chemistry review

Hund’s rule

Written by the Fiveable Content Team • Last updated September 2025
Written by the Fiveable Content Team • Last updated September 2025

Definition

Hund's rule states that every orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied, and all electrons in singly occupied orbitals have the same spin. This principle minimizes electron-electron repulsions and stabilizes the atom.