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Pauli exclusion principle

Definition

The Pauli Exclusion Principle states that no two electrons in an atom can have the same set of four quantum numbers. This principle helps determine electron configurations within atoms, crucial for understanding chemical bonding and molecular structure in organic chemistry.

Analogy

Imagine a school where each classroom (atom) has seats (orbitals) labeled with unique combinations of four details: floor number (principal quantum number), room shape (angular momentum quantum number), seat row orientation (magnetic quantum number), and seat color (spin quantum number). According to the school's rule (Pauli Exclusion Principle), no two students (electrons) are allowed to occupy the same seat (have the same set of four details). This ensures every student has a unique place, just as each electron in an atom must have a unique set of quantum numbers.

Related terms

Quantum Numbers: Quantum numbers describe values of conserved quantities in the dynamics of a quantum system, essentially acting as coordinates for electrons.

Orbital: An orbital is a region in an atom where there is a high probability of finding electrons, defined by specific shapes and energy levels.

Electron Configuration: Electron configuration refers to the distribution of electrons of an atom or molecule in atomic or molecular orbitals

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AP® and SAT® are trademarks registered by the College Board, which is not affiliated with, and does not endorse this website.