🥼organic chemistry review

Dess–Martin periodinane

Written by the Fiveable Content Team • Last updated September 2025
Written by the Fiveable Content Team • Last updated September 2025

Definition

Dess–Martin periodinane is a chemical reagent used in organic chemistry for the oxidation of primary and secondary alcohols to aldehydes and ketones, respectively, without overoxidizing to carboxylic acids. It is favored for its mildness and selectivity in these transformations.

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