๐Ÿ’intro to chemistry review

Second law of thermodynamics

Written by the Fiveable Content Team โ€ข Last updated September 2025
Written by the Fiveable Content Team โ€ข Last updated September 2025

Definition

The second law of thermodynamics states that the total entropy of an isolated system can never decrease over time. It implies that natural processes increase the overall disorder or randomness of a system.

5 Must Know Facts For Your Next Test

  1. Entropy tends to increase in spontaneous processes.
  2. Heat cannot spontaneously flow from a colder body to a hotter body.
  3. The second law introduces the concept of irreversibility in natural processes.
  4. It explains why perpetual motion machines of the second kind are impossible.
  5. The second law is fundamental in understanding energy efficiency and heat engines.

Review Questions

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