Written by the Fiveable Content Team โข Last updated September 2025
Verified for the 2026 exam
Verified for the 2026 examโขWritten by the Fiveable Content Team โข Last updated September 2025
Definition
Entropy is a thermodynamic property that measures the degree of disorder or randomness in a system. It quantifies how spread out or dispersed the energy and particles are within a system.
States that in any spontaneous process, the total entropy of an isolated system always increases over time.
Boltzmann's Formula: Relates entropy to the number of microstates (possible arrangements) corresponding to a given macrostate (observable properties) of a system.
Gibbs Free Energy: Combines enthalpy (heat content) and entropy to determine whether a reaction will be spontaneous at constant temperature and pressure.