💏intro to chemistry review

Born-Haber cycle

Written by the Fiveable Content Team • Last updated August 2025
Written by the Fiveable Content Team • Last updated August 2025

Definition

The Born-Haber cycle is a thermochemical cycle used to analyze the steps in the formation of an ionic compound from its elements. It helps determine lattice energy by considering enthalpy changes during various stages.

AP course connection

Topic 7.5: 7.5 Strengths of Ionic and Covalent Bonds

Unit 7

5 Must Know Facts For Your Next Test

  1. The Born-Haber cycle involves several steps: sublimation, ionization, bond dissociation, electron affinity, and lattice energy.
  2. It is based on Hess's Law which states that the total enthalpy change in a reaction is the same regardless of the number of steps.
  3. Lattice energy can be calculated indirectly using the Born-Haber cycle.
  4. Each step in the Born-Haber cycle corresponds to a specific enthalpy change such as ionization energy or electron affinity.
  5. The cycle provides insight into the stability and strength of ionic bonds.

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