🥼organic chemistry review

Allylic

Written by the Fiveable Content Team • Last updated August 2025
Written by the Fiveable Content Team • Last updated August 2025

Definition

In organic chemistry, an allylic position refers to the next carbon atom adjacent to a double bond in an alkene. This position is significant due to its unique reactivity, particularly in the context of allylic bromination where it can be selectively halogenated.

AP course connection

Topic 10.3: 10.3 Preparing Alkyl Halides from Alkenes: Allylic Bromination

Unit 10
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