A first-order maximum is the first bright fringe observed in a diffraction pattern, occurring at an angle where constructive interference happens for the first time. This angle is determined by the path difference between light waves from adjacent slits in a diffraction grating, leading to a condition that enhances the light intensity. Understanding the first-order maximum helps explain how light behaves when it passes through closely spaced slits, showcasing the wave nature of light and the principles of interference.