Latent heat of fusion is the amount of energy required to change a substance from a solid to a liquid at its melting point, without changing its temperature. This process is crucial for understanding the physical properties of water, as it involves the breaking of intermolecular bonds between water molecules, allowing them to transition from a rigid crystalline structure to a more fluid state. In the context of water, the latent heat of fusion is significant because it plays a key role in climate regulation and biological processes.