The hα line is a specific spectral line in the Balmer series of hydrogen, corresponding to a transition of an electron from the third energy level (n=3) to the second energy level (n=2). This transition results in the emission of light at a wavelength of approximately 656.3 nm, which falls within the red region of the visible spectrum. The hα line is significant in understanding the electronic structure of hydrogen and is used extensively in astrophysics for analyzing stellar atmospheres and nebulae.