🥼organic chemistry review

Olefin metathesis polymerization

Written by the Fiveable Content Team • Last updated September 2025
Written by the Fiveable Content Team • Last updated September 2025

Definition

Olefin metathesis polymerization is a chemical reaction that transforms olefins, which are unsaturated hydrocarbons containing carbon-carbon double bonds, into polymers through the exchange of alkylene groups. This process relies on catalysts to break and reform the double bonds in a way that creates long polymer chains.