🥼organic chemistry review

Molar absorptivity (ε)

Written by the Fiveable Content Team • Last updated September 2025
Written by the Fiveable Content Team • Last updated September 2025

Definition

Molar absorptivity, denoted as ε, is a measure of how well a chemical species absorbs light at a given wavelength, expressed in units of L mol^-1 cm^-1. It quantifies the capacity of molecules, particularly conjugated compounds, to absorb ultraviolet (UV) or visible light, which is fundamental in understanding their electronic structure and behavior.