🥼organic chemistry review

Halonium ion

Written by the Fiveable Content Team • Last updated September 2025
Written by the Fiveable Content Team • Last updated September 2025

Definition

A halonium ion is an intermediate species formed during the addition of a halogen (X2) to an alkene, characterized by a three-membered ring structure consisting of two carbon atoms and one halogen atom. This positively charged ion is highly reactive and plays a crucial role in facilitating the addition of halogens across the double bond of alkenes.