🥼organic chemistry review

Electrophilic aromatic substitution

Written by the Fiveable Content Team • Last updated September 2025
Written by the Fiveable Content Team • Last updated September 2025

Definition

Electrophilic aromatic substitution is a chemical reaction in which an atom, typically hydrogen, attached to an aromatic system, such as benzene, is replaced by an electrophile. This process preserves the aromaticity of the compound while introducing a functional group.

"Electrophilic aromatic substitution" also found in: