🥼organic chemistry review

Carbene, R2C

Written by the Fiveable Content Team • Last updated September 2025
Written by the Fiveable Content Team • Last updated September 2025

Definition

A carbene is a highly reactive molecule consisting of a carbon atom with two unshared electrons bonded to two groups (R), where R can be hydrogen, alkyl, or other substituents. In organic chemistry, carbenes are known for their role in inserting into C-H bonds and adding across double bonds, such as in the synthesis of cyclopropanes from alkenes.