🥼organic chemistry review

Bromonium ion

Written by the Fiveable Content Team • Last updated September 2025
Written by the Fiveable Content Team • Last updated September 2025

Definition

A bromonium ion is a reactive intermediate formed during the halogenation of alkenes when a bromine molecule reacts with an alkene to form a cyclic structure where the bromine atom is covalently bonded to two carbon atoms. This ion is positively charged and highly electrophilic, making it susceptible to nucleophilic attack.