Hemicellulose is a complex carbohydrate that forms a crucial part of the plant cell wall, working alongside cellulose and lignin to provide structural support. It is composed of various sugar monomers, including xylose, arabinose, mannose, and galactose, making it more branched and less crystalline than cellulose. Hemicellulose plays a significant role in cell wall integrity and flexibility, contributing to the overall mechanical properties of the plant cell wall.