Potassium-argon dating is a radiometric dating method used to determine the age of rocks and fossils by measuring the ratio of radioactive potassium-40 to argon-40. This technique is particularly useful for dating volcanic rock and ash layers, as potassium is abundant in these materials. The method relies on the fact that potassium-40 decays into argon-40 over a known time period, allowing scientists to calculate the age of a sample based on the remaining potassium content.