Written by the Fiveable Content Team • Last updated September 2025
Written by the Fiveable Content Team • Last updated September 2025
Definition
Critical pressure is the minimum pressure required to liquefy a gas at its critical temperature. It marks the endpoint of the liquid-vapor phase boundary.
5 Must Know Facts For Your Next Test
Critical pressure is specific to each substance and varies based on molecular characteristics.
At the critical pressure and critical temperature, the substance exists as a supercritical fluid with properties of both liquid and gas.
Water's critical pressure is approximately 22.064 MPa (megapascals).
Above the critical pressure, increasing temperature does not cause a phase change from liquid to gas.
The concept of critical pressure is crucial for understanding phase diagrams and predicting phase changes in gases.