Written by the Fiveable Content Team • Last updated September 2025
Written by the Fiveable Content Team • Last updated September 2025
Definition
Atomic de-excitation occurs when an excited electron in an atom returns to a lower energy state, releasing energy in the form of a photon. This process is fundamental to phenomena such as fluorescence and the emission spectra of elements.
5 Must Know Facts For Your Next Test
During atomic de-excitation, the energy difference between the higher and lower energy states is emitted as a photon.
The wavelength (and thus color) of the emitted photon depends on the energy difference between the two states.
Atomic de-excitation can be spontaneous or stimulated; in spontaneous emission, it happens naturally without external influence.
De-excitation processes are crucial for understanding how lasers work through stimulated emission.
Spectroscopic techniques often rely on observing photons emitted during atomic de-excitations to identify elements.
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Related terms
Photon: A particle representing a quantum of light or other electromagnetic radiation, which carries energy proportional to its frequency.