Written by the Fiveable Content Team โข Last updated September 2025
Written by the Fiveable Content Team โข Last updated September 2025
Definition
The root mean square speed (urms) of gas particles is a measure of the average speed of particles in a gas. It is derived from the kinetic energy of the gas molecules and provides insight into their motion at a given temperature.
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urms can be calculated using the formula $u_{rms} = \sqrt{\frac{3RT}{M}}$, where R is the gas constant, T is the temperature in Kelvin, and M is the molar mass of the gas.
The urms increases with increasing temperature since higher temperatures provide more kinetic energy to gas molecules.
Lighter gases will have a higher urms compared to heavier gases at the same temperature because urms inversely depends on molar mass.
urms is one of three ways to express molecular speeds in gases, along with average speed and most probable speed.