Written by the Fiveable Content Team โข Last updated September 2025
Written by the Fiveable Content Team โข Last updated September 2025
Definition
Thermochemistry is the study of the heat energy involved in chemical reactions and changes of state. It focuses on how energy is absorbed or released during these processes.
5 Must Know Facts For Your Next Test
The first law of thermodynamics states that energy cannot be created or destroyed, only transferred or converted.
Enthalpy ($\Delta H$) is a measure of the total energy of a system, including internal energy and the energy required to make space for it by displacing its environment.
Exothermic reactions release heat into their surroundings, resulting in a negative $\Delta H$ value.
Endothermic reactions absorb heat from their surroundings, resulting in a positive $\Delta H$ value.
Hess's Law states that the total enthalpy change for a reaction is the same, no matter how many steps the reaction is carried out in.
A thermodynamic quantity equivalent to the total heat content of a system. It is equal to the internal energy of the system plus the product of pressure and volume.