Written by the Fiveable Content Team โข Last updated September 2025
Written by the Fiveable Content Team โข Last updated September 2025
Definition
Isoelectronic describes atoms, ions, or molecules that have the same number of electrons or the same electronic structure. This often results in similar chemical properties.
5 Must Know Facts For Your Next Test
Isoelectronic species have identical electron configurations but may differ in nuclear charge.
Common examples include $\text{Ne}$ and $\text{Na}^+$, both with 10 electrons.
When comparing isoelectronic species, the one with the higher positive charge usually has a smaller radius due to increased nuclear attraction.
Isoelectronic series can include both neutral atoms and ions.
Recognizing isoelectronic relationships helps predict chemical behavior and bonding patterns.