Written by the Fiveable Content Team โข Last updated September 2025
Written by the Fiveable Content Team โข Last updated September 2025
Definition
Ionic solids are a type of crystalline solid composed of ions held together by strong electrostatic forces (ionic bonds). They typically form when metals react with non-metals.
5 Must Know Facts For Your Next Test
Ionic solids have high melting and boiling points due to the strength of the ionic bonds.
They are usually hard and brittle, breaking along specific planes.
In solid form, ionic solids do not conduct electricity; however, they can conduct electricity when melted or dissolved in water.
The lattice structure of ionic solids is highly ordered and maximizes the attraction between oppositely charged ions while minimizing repulsion between like charges.
Common examples include table salt (NaCl), magnesium oxide (MgO), and calcium fluoride (CaF_2).
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Related terms
Covalent Solids: Solids where atoms are bonded by covalent bonds forming a continuous network throughout the material.