Written by the Fiveable Content Team โข Last updated September 2025
Written by the Fiveable Content Team โข Last updated September 2025
Definition
Diprotic acids are acids that can donate two protons (hydrogen ions) per molecule in a reaction. They undergo two dissociation steps, each with its own equilibrium constant.
5 Must Know Facts For Your Next Test
Diprotic acids have two dissociation constants: $K_{a1}$ for the first dissociation and $K_{a2}$ for the second.
Common examples of diprotic acids include sulfuric acid ($H_2SO_4$) and carbonic acid ($H_2CO_3$).
The first dissociation step of a diprotic acid usually occurs more readily than the second due to higher acidity.
In aqueous solutions, diprotic acids can form intermediate species such as $HSO_4^-$ or $HCO_3^-$.
Calculations involving diprotic acids often require solving quadratic equations to find pH and concentration of species.
Review Questions
Related terms
Monoprotic Acid: An acid that can donate only one proton per molecule in a reaction.
$K_a$ (Acid Dissociation Constant): $K_a$ is a measure of the strength of an acid in solution, representing the equilibrium constant for its dissociation into ions.
Polyprotic Acid: An acid capable of donating more than one proton per molecule, including diprotic and triprotic acids.