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Body-centered cubic unit cell

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Intro to Chemistry

Definition

A body-centered cubic (BCC) unit cell is a type of crystal structure in which each cube-shaped unit cell has an atom at each of its eight corners and one atom at the center. The BCC structure is less densely packed than the face-centered cubic (FCC) structure but more so than the simple cubic (SC) structure.

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5 Must Know Facts For Your Next Test

  1. Each body-centered cubic unit cell contains a total of 2 atoms: 1/8th of an atom from each of the 8 corners and 1 whole atom at the center.
  2. The coordination number, which is the number of nearest neighbors, for a BCC structure is 8.
  3. The packing efficiency of a BCC structure is approximately 68%, meaning that 68% of the volume in a BCC crystal is occupied by atoms.
  4. Examples of elements with a BCC crystal structure include iron (at room temperature), chromium, and tungsten.
  5. The edge length $a$ and atomic radius $r$ relationship for a BCC unit cell is $a = \frac{4r}{\sqrt{3}}$.

Review Questions

  • How many atoms are there in a single body-centered cubic unit cell?
  • What is the coordination number for a body-centered cubic unit cell?
  • Provide an example of an element that crystallizes in a body-centered cubic structure.

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