๐Ÿ’inorganic chemistry ii review

Simple cubic packing

Written by the Fiveable Content Team โ€ข Last updated September 2025
Written by the Fiveable Content Team โ€ข Last updated September 2025

Definition

Simple cubic packing refers to a type of crystal structure where atoms are arranged in a three-dimensional grid, with one atom located at each corner of a cube. This arrangement allows for a straightforward and organized packing of atoms, but it is not the most efficient in terms of space utilization compared to other packing arrangements. In simple cubic packing, each atom touches its neighbors along the edges of the cube.

5 Must Know Facts For Your Next Test

  1. In simple cubic packing, each unit cell contains only one atom due to the positioning of atoms at the eight corners of the cube.
  2. The coordination number for simple cubic packing is 6, meaning each atom is in contact with six other atoms.
  3. Simple cubic packing has a packing efficiency of approximately 52%, making it less efficient than close-packed structures.
  4. This type of packing is often seen in certain metals like polonium and some alkali metals under specific conditions.
  5. In a simple cubic lattice, the edge length 'a' is related to the atomic radius 'r' by the equation: $$a = 2r$$.

Review Questions

  • How does the packing efficiency of simple cubic packing compare to that of close-packed structures?
    • Simple cubic packing has a packing efficiency of about 52%, which is significantly lower than close-packed structures like face-centered cubic (FCC) and hexagonal close-packed (HCP), which have efficiencies around 74%. This means that while simple cubic packing provides a straightforward arrangement, it leaves more empty space within the crystal lattice compared to these more efficient arrangements. The lower efficiency can impact properties such as density and stability.
  • Discuss the significance of coordination number in understanding simple cubic packing and its implications for atomic interactions.
    • The coordination number in simple cubic packing is 6, indicating that each atom is surrounded by six nearest neighbors. This coordination plays a critical role in determining the physical properties of materials, such as strength and melting point. In contrast, structures with higher coordination numbers, like body-centered cubic (BCC) or face-centered cubic (FCC), tend to have different mechanical properties due to their more complex interactions and arrangements of atoms.
  • Evaluate how the simple cubic packing structure can affect the overall physical properties of materials, particularly in metals.
    • The simple cubic packing structure influences various physical properties such as density, conductivity, and malleability in materials. Due to its lower packing efficiency and coordination number, materials with a simple cubic structure may exhibit lower density and mechanical strength compared to those with more efficient packing arrangements like FCC or BCC. Furthermore, this arrangement affects how atoms interact during deformation or under stress, ultimately impacting the material's usability in applications such as construction or electronics.