The coordinates of points on the unit circle refer to the pairs of values (x, y) that define the location of a point on the circle with a radius of 1 centered at the origin of a coordinate plane. Each point corresponds to an angle measured in radians from the positive x-axis, and these coordinates can be expressed as (cos(θ), sin(θ)), where θ is the angle. This connection between angles and coordinates is crucial for understanding trigonometric functions and their applications.