Log Mean Temperature Difference (LMTD) is a mathematical expression used to calculate the temperature driving force in heat exchangers, allowing for the evaluation of thermal performance. This concept is especially important when dealing with systems where temperature changes non-linearly along the heat exchanger's length, making it essential for precise calculations in both the LMTD method and the effectiveness-NTU method. By providing an average temperature difference, LMTD simplifies complex temperature profiles, enabling better design and analysis of thermal systems.