The complementary error function, denoted as 'erfc', is a mathematical function that describes the probability of a random variable falling outside a specified range for normally distributed data. It is defined as 'erfc(x) = 1 - erf(x)', where 'erf' is the error function, which quantifies the probability of a value being within the range. In the context of transient diffusion, this function is crucial for solving problems involving unsteady state heat conduction and mass transfer.