Pascal's Rule is a fundamental principle in combinatorics that relates binomial coefficients, stating that for any non-negative integers $n$ and $k$, the equation $$\binom{n}{k} = \binom{n-1}{k-1} + \binom{n-1}{k}$$ holds true. This rule highlights the relationship between combinations and allows for the recursive construction of Pascal's Triangle, which is crucial for understanding properties of binomial coefficients and their applications in probability and algebra.