Local thermodynamic equilibrium refers to a condition in which a small region of a system is in thermal equilibrium, meaning that the temperature, pressure, and density are uniform throughout that region and can be described by thermodynamic variables. In the context of stellar structure, it implies that within small enough volumes of a star, the matter behaves as if it were in a state of thermodynamic balance, allowing for the use of classical thermodynamics to describe processes occurring in stars.