Written by the Fiveable Content Team • Last updated August 2025
Written by the Fiveable Content Team • Last updated August 2025
Definition
Free charges are electric charges that are not bound to atoms or molecules and can move freely within a material. In conductors, free charges are typically electrons that respond to electric fields.
In conductors, free charges can move throughout the material, allowing for electrical conductivity.
When an external electric field is applied to a conductor, free charges redistribute themselves until the internal electric field cancels the external one.
Free charges in a conductor at electrostatic equilibrium reside on the surface of the conductor.
The distribution of free charges on a conductor's surface ensures that the electric field inside the conductor is zero in static equilibrium.
Free charge density is often used to describe how much free charge exists per unit volume or surface area.