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Tetrahedral

Written by the Fiveable Content Team • Last updated August 2025
Written by the Fiveable Content Team • Last updated August 2025

Definition

A tetrahedral molecular geometry involves a central atom bonded to four surrounding atoms, situated at the corners of a tetrahedron. The bond angles between the atoms are approximately 109.5 degrees.

5 Must Know Facts For Your Next Test

  1. The ideal bond angle in a perfect tetrahedral molecule is 109.5 degrees.
  2. Methane (CH₄) is a classic example of a molecule with a tetrahedral geometry.
  3. Tetrahedral geometry occurs when there are four bonding pairs and no lone pairs on the central atom.
  4. The hybridization associated with tetrahedral geometry is sp³.
  5. Tetrahedral molecules are generally non-polar if all four substituents are identical.

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