💏intro to chemistry review

Pidgeon process

Written by the Fiveable Content Team • Last updated August 2025
Written by the Fiveable Content Team • Last updated August 2025

Definition

The Pidgeon process is a method for extracting magnesium from its ores using silicon as a reducing agent. It involves heating dolomite in the presence of ferrosilicon to produce magnesium vapor.

5 Must Know Facts For Your Next Test

  1. The Pidgeon process was developed by Lloyd Montgomery Pidgeon in the 1940s.
  2. Dolomite (CaMg(CO3)2) and ferrosilicon are the primary raw materials used in this process.
  3. The chemical reaction involved is: 2CaO⋅2MgO + Si → 2Mg + Ca2SiO4.
  4. Magnesium vapor produced is then condensed into solid magnesium.
  5. This method is energy-intensive and has largely been replaced by more efficient processes like the electrolytic reduction of magnesium chloride.
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