Written by the Fiveable Content Team • Last updated August 2025
Written by the Fiveable Content Team • Last updated August 2025
Definition
Mole fraction (X) is a dimensionless quantity that represents the ratio of moles of a component to the total moles in a mixture. It is used to express the concentration of each component in gaseous mixtures.
Mole fraction can be calculated using $X_i = \frac{n_i}{n_{total}}$, where $n_i$ is the number of moles of component $i$ and $n_{total}$ is the total number of moles in the mixture.
The sum of all mole fractions in a mixture always equals 1, i.e., $\sum X_i = 1$.
Mole fractions are essential for calculating partial pressures in gas mixtures using Dalton's Law: $P_i = X_i \times P_{total}$.
Mole fraction is useful in stoichiometry for determining the proportions of reactants and products in gaseous reactions.
Mole fractions do not have units because they are ratios.