Refutation completeness is a property of a logical system where, if a set of sentences is unsatisfiable, there exists a finite refutation or contradiction derivable from that set using the rules of the system. This concept plays a crucial role in the context of resolution, as it ensures that if a conclusion cannot be true, the system will successfully demonstrate this through resolution refutations. It underscores the effectiveness and limitations of resolution as a proof technique in propositional and first-order logic.