Negation normal form (NNF) is a way of structuring logical formulas where all negations are applied only to atomic propositions, and the formula is composed using only conjunctions (ANDs) and disjunctions (ORs). This format simplifies the analysis of logical expressions by ensuring that negations do not apply to complex formulas or compound statements. NNF is closely related to other normal forms like conjunctive and disjunctive forms, which focus on the arrangement of logical connectives.