🧂physical chemistry ii review

key term - Molecular weight

Definition

Molecular weight is the mass of a single molecule of a substance, typically measured in atomic mass units (amu) or grams per mole (g/mol). It plays a crucial role in understanding the behavior of polymers and how they are formed through different polymerization mechanisms. By knowing the molecular weight, one can deduce information about the properties of the polymer, such as its strength, elasticity, and processing characteristics.

5 Must Know Facts For Your Next Test

  1. Molecular weight is determined by summing the atomic weights of all the atoms in a molecule, and it directly affects the physical properties of polymers.
  2. In polymer science, molecular weight distribution is important; it refers to the range of molecular weights present in a sample, impacting characteristics like toughness and viscosity.
  3. Higher molecular weights usually indicate stronger polymers due to increased chain entanglement, which contributes to better mechanical properties.
  4. The methods used to determine molecular weight include gel permeation chromatography (GPC) and light scattering techniques.
  5. For practical applications, knowing the molecular weight helps in predicting how a polymer will behave under different conditions, such as temperature and stress.

Review Questions

  • How does molecular weight influence the properties of a polymer?
    • Molecular weight significantly affects various properties of a polymer, including its strength, elasticity, and thermal stability. Higher molecular weights often lead to increased intermolecular forces due to greater chain entanglement, enhancing mechanical strength and durability. Conversely, lower molecular weights may result in a more flexible but less strong material. Thus, understanding the relationship between molecular weight and polymer characteristics is crucial for tailoring materials for specific applications.
  • What are the implications of molecular weight distribution in polymers regarding their processing and application?
    • Molecular weight distribution plays a key role in determining how a polymer behaves during processing and its performance in applications. A narrow distribution usually leads to consistent processing behavior and predictable performance characteristics, while a broad distribution can result in variations in flow properties and mechanical strength. This variability can affect how well the polymer processes in applications such as molding or extrusion, making it essential for engineers to consider when designing products.
  • Evaluate how different polymerization mechanisms affect the resulting molecular weight of the final product.
    • Different polymerization mechanisms, such as addition polymerization and condensation polymerization, have distinct effects on the resulting molecular weight. In addition polymerization, molecular weight tends to be high due to continuous chain growth with minimal by-products, while condensation polymerization often results in lower molecular weights since it involves step-growth reactions where small molecules are lost during formation. Analyzing these mechanisms provides insights into how tailored processes can produce polymers with specific desired molecular weights that align with their intended uses.