Organic Chemistry II

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Atom economy

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Organic Chemistry II

Definition

Atom economy is a measure of the efficiency of a chemical reaction in terms of how well atoms from the reactants are utilized in the final products. A higher atom economy indicates that more of the reactant atoms are incorporated into the desired product, reducing waste and improving sustainability. This concept is critical for developing synthetic strategies that prioritize minimizing waste and maximizing resource efficiency in chemical processes.

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5 Must Know Facts For Your Next Test

  1. Atom economy is calculated by dividing the molecular weight of the desired product by the total molecular weight of all reactants, then multiplying by 100 to get a percentage.
  2. Reactions with high atom economy typically produce fewer by-products, which aligns with principles of green chemistry aimed at reducing waste.
  3. For example, in a reaction where two reactants combine to form one product, the atom economy would be 100%, while reactions that generate multiple by-products have lower atom economies.
  4. Improving atom economy is not only beneficial for environmental reasons but can also lead to cost savings in industrial processes due to reduced raw material usage.
  5. Atom economy is especially important when considering large-scale production in industries like pharmaceuticals, where efficient use of resources can significantly impact overall sustainability.

Review Questions

  • How does atom economy influence the selection of synthetic routes in chemical synthesis?
    • Atom economy plays a critical role in choosing synthetic routes as it helps chemists evaluate the efficiency of reactions. Routes with higher atom economy are preferred because they utilize more reactant atoms in the final product, which reduces waste and enhances sustainability. By focusing on reactions that optimize atom economy, chemists can design processes that are not only cost-effective but also environmentally friendly.
  • Discuss the relationship between atom economy and green chemistry principles in developing new synthetic strategies.
    • The relationship between atom economy and green chemistry principles is fundamental for promoting sustainable practices in chemical synthesis. Green chemistry emphasizes minimizing waste and using safer materials, which aligns perfectly with high atom economy. Strategies that improve atom economy contribute to these goals by ensuring that more reactant atoms are converted into useful products rather than by-products, thus enhancing both economic and environmental outcomes.
  • Evaluate how increasing atom economy can impact both environmental sustainability and economic viability in industrial processes.
    • Increasing atom economy has profound implications for both environmental sustainability and economic viability in industrial processes. By maximizing the incorporation of reactant atoms into products, companies can significantly reduce waste generation, leading to lower disposal costs and decreased environmental impact. Economically, higher atom economies can enhance profitability by reducing raw material costs and improving overall production efficiency, making processes more attractive for industries focused on sustainability while still achieving financial success.
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