key term - Sodium Hydroxide

Definition

Sodium hydroxide, also known as caustic soda or lye, is a highly alkaline and corrosive chemical compound that plays a crucial role in various organic chemistry processes, including the oxidation of alkenes, the nucleophilic addition of water, and the production of soap.

5 Must Know Facts For Your Next Test

1. Sodium hydroxide is a strong base with a high pH, typically around 14, making it a highly reactive and corrosive chemical.
2. In the context of the oxidation of alkenes, sodium hydroxide is used in the epoxidation reaction, where it helps to form an epoxide intermediate.
3. During the nucleophilic addition of water, sodium hydroxide can act as a catalyst, facilitating the addition of water to an alkene and the formation of an alcohol.
4. In the production of soap, sodium hydroxide is a key ingredient in the saponification reaction, where it reacts with fats or oils to produce soap and glycerol.
5. Sodium hydroxide is a versatile chemical with a wide range of applications, including in the production of paper, textiles, and various other industrial processes.

Review Questions

• Explain the role of sodium hydroxide in the epoxidation of alkenes.
  • In the oxidation of alkenes, sodium hydroxide is used in the epoxidation reaction. The sodium hydroxide helps to form an epoxide intermediate, a cyclic ether, by adding an oxygen atom to the double bond of the alkene. This epoxidation reaction is a crucial step in the synthesis of various organic compounds and is often used in the production of pharmaceuticals and other fine chemicals.
• Describe how sodium hydroxide facilitates the nucleophilic addition of water to alkenes.
  • During the nucleophilic addition of water to alkenes, sodium hydroxide can act as a catalyst. The hydroxide ion (OH-) from the sodium hydroxide serves as a nucleophile, attacking the carbon-carbon double bond of the alkene and facilitating the addition of water. This reaction results in the formation of an alcohol, which is an important class of organic compounds with various applications in chemistry and industry.
• Analyze the role of sodium hydroxide in the saponification reaction during the production of soap.
  • In the production of soap, sodium hydroxide is a key ingredient in the saponification reaction. During this process, the sodium hydroxide reacts with fats or oils, which are composed of triglycerides, to produce soap and glycerol. The hydroxide ion from the sodium hydroxide acts as a nucleophile, attacking the carbonyl carbon of the triglycerides and breaking the ester bonds. This reaction leads to the formation of soap, a salt of a fatty acid, and glycerol, a byproduct. The soap produced through this saponification reaction is widely used for cleaning and personal care applications.

Related terms

Epoxidation:

A chemical reaction in which an alkene is converted into an epoxide, a cyclic ether, using a peroxyacid or a peroxide as the oxidizing agent.

Hydration:

A chemical reaction in which a molecule of water is added to a compound, typically resulting in the formation of a new compound.

Saponification:

The process of converting fats or oils into soap by the action of an alkali, such as sodium hydroxide, on the triglycerides present in the fats or oils.