key term - Free Radical

Definition

A free radical is a highly reactive chemical species that contains an unpaired electron in its outer shell. These unstable molecules are constantly seeking to pair up their unpaired electron, making them highly reactive and capable of initiating chain reactions in various chemical processes, including those involved in the formation of chain-growth polymers and biological additions to alkenes.

5 Must Know Facts For Your Next Test

1. Free radicals are highly reactive due to the presence of an unpaired electron, which makes them seek to pair up with other electrons, initiating chain reactions.
2. In the context of radical additions to alkenes, free radicals can add to the carbon-carbon double bond, leading to the formation of chain-growth polymers.
3. Biological additions of radicals to alkenes, such as those found in living organisms, can also involve free radical intermediates and play a role in various metabolic processes.
4. Chain-growth polymers, like those formed in radical polymerization, rely on the propagation of free radical intermediates to continue the growth of the polymer chain.
5. Free radicals can be generated through various means, including thermal decomposition, photochemical reactions, and redox processes, and their reactivity can be influenced by factors such as solvent, temperature, and the presence of other chemical species.

Review Questions

• Explain how the presence of an unpaired electron in a free radical contributes to its high reactivity and ability to initiate chain reactions.
  • The unpaired electron in a free radical makes the molecule highly reactive, as it is constantly seeking to pair up with another electron to achieve a more stable electronic configuration. This high reactivity allows free radicals to readily participate in chain reactions, where the initial free radical can abstract an electron from another molecule, creating a new free radical that can then propagate the reaction. This self-propagating nature of chain reactions is a key feature that enables the rapid formation of products, such as in the case of chain-growth polymerization.
• Describe the role of free radicals in the formation of chain-growth polymers and biological additions to alkenes.
  • Free radicals play a crucial role in the formation of chain-growth polymers, such as those discussed in Section 8.10. In these reactions, the free radical can add to the carbon-carbon double bond of an alkene monomer, creating a new free radical that can then continue to propagate the growth of the polymer chain. Similarly, in biological systems (as discussed in Section 8.11), free radical intermediates can be involved in the addition of various species to alkenes, contributing to important metabolic processes. The ability of free radicals to initiate and propagate these chain reactions is a defining characteristic that allows for the efficient synthesis of complex polymeric materials and the regulation of biological pathways.
• Analyze how the reactivity of free radicals can be influenced by factors such as solvent, temperature, and the presence of other chemical species, and explain how these factors may impact the outcomes of reactions involving free radicals.
  • The reactivity of free radicals can be significantly influenced by various factors, such as the solvent, temperature, and the presence of other chemical species. The solvent can affect the stability and reactivity of free radicals through solvation effects and the ability to stabilize or destabilize the radical intermediates. Temperature can also play a crucial role, as increased temperatures can promote the formation of free radicals through thermal decomposition or other activation processes, while also potentially accelerating the rate of chain reactions. Additionally, the presence of other chemical species, such as inhibitors or promoters, can modulate the reactivity and behavior of free radicals, either by scavenging them, altering their electronic properties, or influencing the overall reaction kinetics. Understanding how these factors can impact the reactivity of free radicals is essential for the successful design and control of chemical processes involving radical intermediates, such as in the synthesis of chain-growth polymers or the regulation of biological pathways.

Related terms

Chain Reaction:

A self-propagating sequence of reactions where a single initiating event can trigger a series of subsequent reactions, leading to the rapid production of a large number of products.

Oxidation:

A chemical reaction that involves the loss of electrons by a molecule, atom, or ion, resulting in an increase in its oxidation state.

Polymerization:

The process of combining many small molecules, called monomers, into a large molecule called a polymer through the formation of covalent bonds.