🔋college physics i – introduction review

Quantum numbers

Written by the Fiveable Content Team • Last updated September 2025
Written by the Fiveable Content Team • Last updated September 2025

Definition

Quantum numbers are sets of numerical values that describe the unique quantum state of an electron in an atom. They provide information about the electron’s energy level, orbital shape, orbital orientation, and spin direction.

5 Must Know Facts For Your Next Test

  1. The four types of quantum numbers are principal ($n$), azimuthal ($l$), magnetic ($m_l$), and spin ($m_s$).
  2. The principal quantum number ($n$) determines the energy level and size of the orbital.
  3. The azimuthal quantum number ($l$) determines the shape of the orbital and ranges from 0 to $n-1$.
  4. The magnetic quantum number ($m_l$) determines the orientation of the orbital in space and ranges from $-l$ to $+l$.
  5. The spin quantum number ($m_s$) describes the intrinsic spin of the electron and can be either $+\frac{1}{2}$ or $-\frac{1}{2}$.

Review Questions

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