Quantum tunneling is a quantum mechanical phenomenon where a particle can pass through a potential energy barrier that it classically should not be able to surmount. This occurs because particles, at the quantum level, do not have definite positions or energies but exist in a range of probabilities, allowing them to 'tunnel' through barriers rather than going over them. This concept plays a crucial role in understanding processes like nuclear fission and fusion, where particles must overcome significant energy barriers to interact and react.