Written by the Fiveable Content Team โข Last updated September 2025
Verified for the 2026 exam
Verified for the 2026 examโขWritten by the Fiveable Content Team โข Last updated September 2025
Definition
Hess's Law states that the total enthalpy change for a chemical reaction is independent of the pathway or number of steps taken to achieve the reaction. It only depends on the initial and final states.
This is the heat content of a system at constant pressure. It's like measuring how much energy (or "heat") is in your lunchbox if it couldn't leak out anywhere.
This type of reaction absorbs heat from its surroundings during its process. Imagine this as an ice cream cone absorbing heat on a hot summer day and melting.
In contrast to endothermic reactions, exothermic reactions release heat into their surroundings. Picture this as lighting up a firework; once ignited, it releases light and heat into the air around it.