🪢intro to polymer science review
12.1 Fiber spinning techniques and equipment
2 min read•Last Updated on July 23, 2024
Fiber spinning techniques are crucial in polymer science, transforming raw materials into usable fibers. Melt, dry, and wet spinning methods each have unique advantages, allowing for the production of various fiber types with specific properties.
The spinning process involves several key components, from extruders to take-up units. Parameters like extrusion temperature and draw ratio significantly impact fiber characteristics, influencing their strength, orientation, and overall quality.
Fiber Spinning Techniques
Fiber spinning techniques
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Top images from around the web for Fiber spinning techniques
Electrospinning: a facile technique for fabricating polymeric nanofibers doped with carbon ... View original
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Unit - Chemistry of Textiles: Synthetic Fibres View original
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Carbon Fiber Technology Facility | Melt Spinning Process Alt… | Flickr View original
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Electrospinning: a facile technique for fabricating polymeric nanofibers doped with carbon ... View original
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Unit - Chemistry of Textiles: Synthetic Fibres View original
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- Melt spinning involves melting a thermoplastic polymer (polyester, nylon) and extruding it through a spinneret, followed by cooling the extruded filaments to solidify them
- Dry spinning dissolves the polymer in a volatile solvent and extrudes the solution through a spinneret into a heated chamber where the solvent evaporates, leaving solid polymer filaments, used for polymers that decompose before melting (acrylic, cellulose acetate)
- Wet spinning dissolves the polymer in a solvent and extrudes the solution through a spinneret into a coagulation bath that removes the solvent by chemical reaction or diffusion, employed for heat-sensitive polymers (rayon, aramid)
Components of spinning equipment
- Extruder melts or dissolves the polymer and pumps the molten polymer or solution through the spinneret
- Spinneret is a metal plate with numerous small holes that shapes the polymer into filaments
- Quenching unit in melt spinning cools and solidifies the extruded filaments using air or water
- Coagulation bath in wet spinning contains a liquid that removes the solvent from the extruded filaments and solidifies them
- Take-up and drawing units collect and stretch the solidified filaments to improve the mechanical properties and orientation of the fibers
Advantages vs limitations of techniques
- Melt spinning advantages: high production rates, low cost, good fiber uniformity; limitations: only applicable to thermoplastic polymers
- Dry spinning advantages: suitable for heat-sensitive polymers, produces high-quality fibers; limitations: slower production rates, solvent recovery is required
- Wet spinning advantages: applicable to heat-sensitive polymers, allows for high draw ratios; limitations: slower production rates, solvent recovery, and wastewater treatment are necessary
Effects of parameters on fibers
- Extrusion temperature: higher temperatures reduce polymer viscosity and improve flow but excessive temperatures may cause polymer degradation
- Spinneret design: hole diameter and shape influence fiber cross-section and size with smaller holes producing finer fibers
- Take-up speed: higher speeds result in increased molecular orientation and improved mechanical properties but excessive speeds may cause fiber breakage
- Draw ratio (final fiber length to initial length): higher draw ratios increase molecular orientation and crystallinity, improving tensile strength and modulus but may reduce elongation at break
- Cooling or coagulation rate: faster cooling or coagulation leads to finer fiber structure and higher amorphous content while slower rates promote crystallization and larger fiber diameters