Unsatisfiability refers to a property of a logical formula where there are no possible interpretations or assignments of truth values that make the formula true. It plays a crucial role in understanding the limits of logical systems and is intimately connected to Skolemization and Herbrand's theorem, which provide ways to analyze the satisfiability of formulas. Additionally, unsatisfiability is significant in unification and the resolution algorithm, as it helps determine whether a given set of statements can be resolved into a contradiction.
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